含有2,4-二卤代联苯基的新型唑类衍生物的合成及其抗真菌活性

以2,4-二卤代联苯为原料,经傅-克酰基化、还原、取代等反应步骤,合成了含有2,4-二卤代联苯基的新型唑类目标化合物3a~3k,其结构用红外光谱(IR)、高分辨质谱(HMRS)、核磁共振氢谱(¹H NMR)、核磁共振碳谱(¹³C NMR)等技术手段进行了表征。 测试了目标化合物的体外抗真菌活性,结果表明,所有目标化合物对所测试的致病真菌均有一定程度的抗真菌活性。 其中化合物3a~3k对红色发癣菌和石膏样毛癣菌的抗真菌活性和两性霉素B相当,化合物3b、3c、3e、3f、3h、3i、3k对白色念珠菌的抗真菌活性优于或等于酮康唑。     

离散大系统在结构扰动下周期解的存在性

对于离散系统稳定性的研究,近年来受到人们的重视,但对于周期解的研究,在文献中还很少看到。本文首先讨论了离散系统解的有界性,并且得到了若一个具有周期系数的差分方程的解为最终有界的,则存在周期解的结果。然后利用李雅普诺夫函数方法研究了离散大系统在结构扰动之下周期解的存在性和离散大系统的平稳振荡。     

The Local Spectral Properties of Extended Hamilton Operators

In this paper, we introduce the class of extended Hamilton operators and study various properties of this class. We examine the decomposability of extended Hamilton operators. In addition,we prove that an extended Hamilton operator with property(δ) is subscalar. Finally, we consider Weyl type theorems of this class.     

On the Global Convergence of a Projective Trust Region Algorithm for Nonlinear Equality Constrained Optimization

A trust-region sequential quadratic programming (SQP) method is developed and analyzed for the solution of smooth equality constrained optimization problems. The trust-region SQP algorithm is based on filter line search technique and a composite-step approach, which decomposes the overall step as sum of a vertical step and a horizontal step. The algorithm includes critical modifications of horizontal step computation. One orthogonal projective matrix of the Jacobian of constraint functions is employed in trust-region subproblems. The orthogonal projection gives the null space of the transposition of the Jacobian of the constraint function. Theoretical analysis shows that the new algorithm retains the global convergence to the first-order critical points under rather general conditions. The preliminary numerical results are reported.     

The James constant for the <Emphasis Type="Italic">l</Emphasis><Subscript>3</Subscript> − <Emphasis Type="Italic">l</Emphasis><Subscript>1</Subscript> space

In this note, the exact value of the James constant for the l₃-l₁ space is obtained, J(l₃-l₁)=1.5573…. This result improves the known inequality, J(l₃-l₁)≤4/³√10, which was given by Dhompongsa, Piraisangjun and Saejung.     

B~n上推广的Roper-Suffridge算子的性质

讨论改进后的Roper-Suffridge延拓算子保持双全纯映照子族的性质.借助双全纯映照子族的解析特征及其偏差结论,得到改进后的Roper-Suffridge延拓算子在一定条件下保持α次殆β型螺形映照、α次β型螺形映照、强β型螺形映照的性质,从而得到改进后的算子在一定条件下保持α次殆星形性、α次星形性和强星形性.所得结论为在多复变数空间中构造这些双全纯映照提供了一种新的途径.     

Immersed Hypersurfaces in the Unit Sphere S^m＋1 with Constant Blaschke Eigenvalues

For an immersed submanifold x ： M^m→ Sn in the unit sphere S^n without umbilics, an eigenvalue of the Blaschke tensor of x is called a Blaschke eigenvalue of x. It is interesting to determine all hypersurfaces in Sn with constant Blaschke eigenvalues. In this paper, we are able to classify all immersed hypersurfaces in S^m＋1 with vanishing MSbius form and constant Blaschke eigenvalues, in case （1） x has exact two distinct Blaschke eigenvalues, or （2） m = 3. With these classifications, some interesting examples are also presented.     

十六烷基三甲基溴化铵敏化孔雀石绿-脱氧核糖核酸的共振光散射增强法测定脱氧核糖核酸

在碱性条件下 ,脱氧核糖核酸 (DNA)对孔雀石绿的共振光散射有增强作用 ,加入十六烷基三甲基溴化铵 (CTMAB)进一步敏化该体系。共振光散射增强的程度与DNA浓度呈良好的线性关系 ,据此建立了测定DNA的共振光散射增强分析方法。在实验条件下 ,最大散射波长 36 4nm处 ,测定小牛胸腺DNA(ctDNA)和鱼精子DNA(fsDNA)的线性范围皆为 0～ 1 5 μg·mL-1,检出限分别为 0 0 5和 0 0 3μg·mL-1。该方法简单、快速、灵敏度高 ,已成功应用于合成样品中DNA含量的测定。     

新型聚合物固体电解质的红外光谱研究

采用微波热交联技术制备出了多孔状的聚偏氟乙烯 /聚甲基丙烯酸甲酯 (PVDF PMMA)共混的聚合物固体电解质薄膜材料 ,电性能测试表明该固体电解质薄膜在室温下的电导率可达到 2 0 5× 10 - 3S·cm- 1 ,并具有良好的机械性能。用红外光谱对该膜进行了分析 ,结果表明在聚合物固态电解质中的PVDF ,PMMA ,LiClO4 和γ 丁内指 (BL)之间并不是简单的混合 ,而是存在着某种相互作用 ,并且这种作用只有在生成聚合物固态电解质时 ,才明显地得到了加强。     

PGB′s Corrections to Top-Quark Production in Topcolor-assisted Multiscale Technicolor Model

In topcolor-assisted multiscale technicolor (TOPCMTC) model.we calculate the corrections of Pseudo Goldstone bosons (technipions,top-pions)to the cross section of the process qq→tt at the Fermilab Tevatron.Our results show that the corrections mainly come form top pions.With reasonable value of the parameters.the correction can increase the total tt production corss section σtt by as much as 17%.This may provide a window to detect tpo-pions.